TITLE: Chabazite HS193 DESCRIPT

DOCUMENTATION_FORMAT: MINERAL

SAMPLE_ID: HS193

MINERAL_TYPE: Tectosilicate

MINERAL: Chabazite (Zeolite group)

FORMULA: CaAl2Si4012*6H2O

FORMULA_HTML: CaAl2Si4012•6H2O

COLLECTION_LOCALITY: Colorado

ORIGINAL_DONOR: Hunt and Salisbury Collection

CURRENT_SAMPLE_LOCATION: USGS Denver Spectroscopy Laboratory

ULTIMATE_SAMPLE_LOCATION: USGS Denver Spectroscopy Laboratory

SAMPLE_DESCRIPTION:

Usually found in rhombohedral chrystals, with nearly cubic angles. The ideal composition listed in the FORMULA field often has considerable replacement of Ca by Na and K as well as (Na,K)Si for CaAl. The structure of chabazite consists of an Al-Si-O framework with large cagelike openings bounded by rings of tetrahedra. The cages are connected to each other by channels which allow diffusion of molecules of less than ~3.9 Angstroms.

The bands seen in its near-infrared spectrum are typical of large quantities of molecular water.

See: Hunt, G.R., J.W. Salisbury, 1970, Visible and near-infrared spectra of minerals and rocks: I. Silicate minerals. Modern Geology, v. 1, p. 283-300.

END_SAMPLE_DESCRIPTION.

XRD_ANALYSIS:

40 kV - 30 mA, 6.5-9.5 keV
File: chab193.out, -.mdi; chabz193.out, -.mdi
References: JCPDS # 34-137, 35-498, 42-1451
Found: Chabazite, thomasite, wairaikite in subequal proportions

Comment: Reflections are sharp and strong, suggesting good crystallinity and compositional homogeneity. Many peak overlaps made interpretation of the pattern very difficult. Consideration of the relative intensities of chabazite and thomasite led to the realization that some sharp peakshad an intensity contribution from a third phase, which turned out to be wairaikite.

J.S.Huebner, J. Pickrell, T. Schaefer, written communication(USGS 1994)

END_XRD_ANALYSIS.

COMPOSITIONAL_ANALYSIS_TYPE: None # XRF, EM(WDS), ICP(Trace), WChem

COMPOSITION_TRACE: None

COMPOSITION_DISCUSSION:

None

END_COMPOSITION_DISCUSSION.

MICROSCOPIC_EXAMINATION:

96 vol% Chabazite
2 vol% other phases including magnetite
2 vol% Fe-stained grains

av gr sz = 275µm

Clear grains, fibrous prismatic cones, low birefringence, very small 2V which is charateristic of the Chabazite group. G. Swayze

END_MICROSCOPIC_EXAMINATION.

SPECTROSCOPIC_DISCUSSION:

END_SPECTROSCOPIC_DISCUSSION.

SPECTRAL_PURITY: 1_2_3_4_

LIB_SPECTRA_HED: where Wave Range Av_Rs_Pwr Comment

LIB_SPECTRA: splib04a r 884 0.2-3.0µm 200 g.s.= 275µm

LIB_SPECTRA: splib05a r ____ 0.2-3.0µm 200 g.s.=

LIB_SPECTRA: splib06a r ____ 1.5-25µm 250 g.s.=